Qualitative analysis of KNN and PZT ceramics by Particle Induced X-Ray Emission and Rutherford Backscattering Spectrometry.

28 Oct 2022, 14:00
1h 30m
Zoom (Online)

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Online

Poster Applied Research Online poster session

Speaker

Javier Pérez Pérez (Institute of Science and Technology of Materials, Havana University)

Description

The first results of scientific cooperation between Cuban and the Joint Institute for Nuclear Research (JINR) of Russian Federation researchers in the application of ion beam analysis (IBA) methods are presented. PIXE and RBS measurements were carried out at the EG-5 accelerator facilities of the Frank Laboratory of Neutron Physics (FLNP)/JINR, contributing this way to the characterization of (K0.44Na0.52Li0.04)0.97La0.01Nb0.9Ta0.1O3 (KNN) and Pb(Zr0.53Ti0.47)O3:Gd (PZT:Gd) ceramic samples.
Samples were prepared at the Center of Nanoscience and Nanotechnology of the National Autonomous University of México (CNyN/UNAM) by researchers from the Faculty of Physics of Havana University, the Cuban Institute of Cybernetic, Mathematics and Physics (ICIMAF) and the CNyN/UNAM. Experimental data processing was achieved in parallel by researchers of the EG-5/FLNP/JINR and the Havana University (Institute of Materials Science and Technology - IMRE and Higher Institute of Technology and Applied Sciences - InSTEC).
As result of PIXE analysis, Na, Ta, Nb and K in one KNN ceramic sample; and Gd, Zr, Ti and Pb in the PZT:Gd ceramic were detected. On the other hand, the concentration profiles of Na, Ta, Nb, K and O in KNN samples, and of Gd, Zr, Ti and Pb in the PZT:Gd sample were obtained by RBS analysis, which was performed by applying the ion beam in two incident directions respect to the sample surface.
The present study is the first step to the further quantitative determination of elemental composition of these samples by IBA.

Primary authors

Javier Pérez Pérez (Institute of Science and Technology of Materials, Havana University) Mario Simeón Pomares Alfonso (Institute of Science and Technology of Materials, Havana University) Edwin Pedrero González (Institute of Science and Technology of Materials, Havana University) Phan Luong Tuan (Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research) Tatyana Yu. Zelenyak (Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research) Anastasia Kruglyak (Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research) Oscar Díaz Rizo (Higher Institute of Technology and Applied Sciences, Havana University) Grizel Pérez Zayas (Higher Institute of Technology and Applied Sciences, Havana University) Jorge Portelles Rodríguez (Faculty of Physics, Havana University) Juan Fuentes Betancourt (Faculty of Physics, Havana University)

Co-authors

A. S. Doroskevich (Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research) J. M. Siqueiros (Center of Nanoscience and Nanothecnology of the National Autonomous University of Mexico ) R. López (Institute of Cybernetic, Mathematics and Physics, Cuban Ministery of Science, Technology and Enviroment ) Y. de Armas (Institute of Cybernetic, Mathematics and Physics, Cuban Ministery of Science, Technology and Enviroment ) J. Rebellón-Watson (Institute of Cybernetic, Mathematics and Physics, Cuban Ministery of Science, Technology and Enviroment ) A. Leyva Fabelo (Center of Technological Applications and Nuclear Development, Cuban Ministery of Science, Technology and Enviroment )

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