Pressure effected phase transition of perovskite like La2Ti2O7

26 Oct 2022, 16:20
15m
Conference hall (MLIT, JINR)

Conference hall

MLIT, JINR

Oral Condensed Matter Physics Condensed Matter Physics

Speaker

Mr Asif Asadov (FLNP)

Description

The crystal structure of lanthanum titanate La2Ti2O7 was investigated by X-ray diffraction and Raman spectroscopy at high pressures up to 32 GPa and for structural determination neutron diffraction done at ambient condition. The La2Ti2O7 structure is monoclinic with the space group P21 at ambient condition. We observed a structural phase transition into the orthorhombic phase with a space group Pna21 at P=17.3 GPa. It was found that the phase transition highly depend on titanium oxide source. Dependences of parameters and volume of the unit cell on the pressure was found, and the bulk modulus has been calculated.

Primary author

Mr Asif Asadov (FLNP)

Co-authors

Dr Rafiqa Mehdiyeva (Institute of Physics, Azerbaijan National Academy of Sciences, Baku AZ-1143, Azerbaijan) Prof. Ali Mammadov (Institute of Physics, Azerbaijan National Academy of Sciences, Baku AZ-1143, Azerbaijan) Dr Denis Kozlenko (Joint Institute for Nuclear Research, Dubna 141980, Russia;) Mr Evgeny Lukin (Joint Institute for Nuclear Research, Dubna 141980, Russia;) Mr Sergey Kichanov (Joint Institute for Nuclear Research, Dubna 141980, Russia;) Mrs Olga Lis (Joint Institute for Nuclear Research, Dubna 141980, Russia;) Mr Anton Rutkauskas (Joint Institute for Nuclear Research, Dubna 141980, Russia;)

Presentation materials